Match the following industrial processes with the catalysts used:

Cracking of hydrocarbons – Fe
Each process is paired with its appropriate catalyst, enhancing the reaction's efficiency. For example, Ostwald's process uses \( \text{CuCl}_2 \) to produce nitric acid from ammonia.
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is
For $\mathrm{A}_{2}+\mathrm{B}_{2} \rightleftharpoons 2 \mathrm{AB}$ $\mathrm{E}_{\mathrm{a}}$ for forward and backward reaction are 180 and $200 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively. If catalyst lowers $\mathrm{E}_{\mathrm{a}}$ for both reaction by $100 \mathrm{~kJ} \mathrm{~mol}^{-1}$. Which of the following statement is correct?
In a messenger RNA molecule, untranslated regions (UTRs) are present at:
I. 5' end before start codon
II. 3' end after stop codon
III. 3' end before stop codon
IV. 5' end after start codon