Match the following:

Step 1: Understanding Refining Methods
- Vapour phase refining (Van Arkel method) is used for metals like Nickel (Ni).
- Zone refining is used for Silicon (Si) and other semiconductors.
- Liquation is used for Tin (Sn) to remove impurities with lower melting points.
- Electrolysis is commonly used for Copper (Cu) purification.
Step 2: Matching Correct Refining Methods
- \( A - V \) (Nickel - Vapour phase refining)
- \( B - I \) (Silicon - Zone refining)
- \( C - II \) (Tin - Liquation)
- \( D - III \) (Copper - Electrolysis)
Step 3: Conclusion
- The correct answer is Option (1): A - V, B - I, C - II, D - III.
Standard electrode potential for \( \text{Sn}^{4+}/\text{Sn}^{2+} \) couple is +0.15 V and that for the \( \text{Cr}^{3+}/\text{Cr} \) couple is -0.74 V. The two couples in their standard states are connected to make a cell. The cell potential will be:
To calculate the cell potential (\( E^\circ_{\text{cell}} \)), we use the standard electrode potentials of the given redox couples.
Given data:
\( E^\circ_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +0.15V \)
\( E^\circ_{\text{Cr}^{3+}/\text{Cr}} = -0.74V \)