Step 1: SE Detector.
- Secondary electrons (SE) are low-energy electrons emitted from near the surface.
- They provide surface-sensitive information.
\[
\Rightarrow \text{SE detector gives a topographic image. (P-3)}
\]
Step 2: BSE Detector.
- Backscattered electrons (BSE) originate from deeper in the sample and depend strongly on atomic number (Z-contrast).
- Regions with higher atomic number appear brighter.
\[
\Rightarrow \text{BSE detector gives compositional contrast images. (Q-4)}
\]
Step 3: EDS Detector.
- Energy Dispersive X-ray Spectroscopy (EDS) detects characteristic X-rays.
- These correspond to the elemental composition of the material.
\[
\Rightarrow \text{EDS detector provides elemental composition analysis. (R-1)}
\]
Step 4: EBSD Detector.
- Electron Backscatter Diffraction (EBSD) patterns give Kikuchi lines.
- These lines are used to determine crystallographic orientation.
\[
\Rightarrow \text{EBSD detector shows Kikuchi lines. (S-2)}
\]
Step 5: Final Matching.
\[
(P, Q, R, S) = (3, 4, 1, 2)
\]
Thus, the correct option is:
\[
\boxed{\text{(D) P-3; Q-4; R-1; S-2}}
\]