Question:

Match List I with List II

List-I
(Complex)

List-II
(Type of isomerism)

(A)[Co(NH3)5(NO2)]Cl2(I)Solvate isomerism
(B)[Co(NH3)5(SO4)]Br(II)Linkage isomerism
(C)[Co(NH3)6] [Cr(CN)6](III)Ionization isomerism
(D)[Co(H2O)6]Cl3(IV)Coordination isomerism

Choose the correct answer from the options given below:

Updated On: Dec 4, 2024
  • A-II, B-III, C-IV, D-I
  • A-I, B-III, C-IV, D-II
  • A-I, B-IV, C-III, D-II
  • A-II, B-IV, C-III, D-I
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The Correct Option is A

Solution and Explanation

- Complex A exhibits ionization isomerism because $NO_2^-$ can ionize.
- Complex B shows solvate isomerism due to $SO_4^{2-}$ exchange with water molecules.
- Complex C shows coordination isomerism between the two metal centers.
- Complex D shows linkage isomerism because $Cl^-$ can bind in multiple ways.

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