Question:

Match List-I with List-II:
List-IList-II
(A) XeF2(iii) Linear
(B) BF3(i) Trigonal Planar
(C) XeF4(ii) Distorted Octahedral
(D) SF6(iv) Regular Octahedral
Choose the correct answer from the options given below:

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VSEPR theory is used to determine molecular geometries by minimizing electron pair repulsions. Lone pairs are more repulsive than bonding pairs and therefore tend to compress bond angles, distorting the geometry from its ideal shape.
Updated On: Jan 2, 2025
  • (A) - (i), (B) - (iii), (C) - (ii), (D) - (iv).
  • (A) - (iii), (B) - (i), (C) - (ii), (D) - (iv).
  • (A) - (iv), (B) - (iii), (C) - (ii), (D) - (i).
  • (A) - (iii), (B) - (iv), (C) - (i), (D) - (ii).
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The Correct Option is B

Solution and Explanation

The molecular geometries are from VSEPR:
\(XeF_2\): Linear due to three lone pairs and two bond pairs.
• \(BF_3\): Trigonal planar due to three bond pairs and no lone pairs.
• \(XeF_4\): Distorted octahedral with four bond pairs and two lone pairs.
• \(SF_6\): Regular octahedral with six bond pairs and no lone pairs.
The correct matching is: (A) - (iii), (B) - (i), (C) - (ii), (D) - (iv).

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