Let's go through each option and match them with the corresponding items in List II.
- (A) Electrolytic reduction: This process involves the reduction of metal ions to metal using electricity. This is commonly used in the extraction of aluminium (III) from its oxide (Al$_2$O$_3$) using the Hall-Héroult process.
\[
\text{2Al}_2\text{O}_3 \xrightarrow{\text{electrolysis}} 4\text{Al} + 3\text{O}_2
\]
So, Electrolytic reduction is related to Aluminium (III).
- (B) Bessemerization: This process is used for converting pig iron to steel by blowing oxygen through it, and it is closely related to the production of Iron (I).
\[
\text{Fe}_2\text{O}_3 + 3\text{C} \xrightarrow{\text{Bessemer process}} 2\text{Fe} + 3\text{CO}
\]
Therefore, Bessemerization is related to Iron (I).
- (C) Smelting: Smelting is a process of extracting metals from ores using heat. It is used to obtain metals like Zinc (II) from their ores (e.g., zinc oxide).
\[
\text{ZnO} + \text{C} \xrightarrow{\text{heat}} \text{Zn} + \text{CO}
\]
So, Smelting is associated with Zinc (II).
- (D) Reduction from oxide: This process is used for extracting metals from their oxides using a reducing agent (usually carbon). Copper (IV) is commonly extracted from its oxide using carbon.
\[
\text{CuO} + \text{C} \xrightarrow{\text{heat}} \text{Cu} + \text{CO}
\]
Hence, Reduction from oxide is related to Copper (IV).
Thus, the correct answer is (A)-(III), (B)-(I), (C)-(II), (D)-(IV).