Question:

Liquid benzene $(C_6H_6)$ bums in oxygen according to the equation, $ \, \, \, \, \, \, 2C_6H_6 (I) + 15O_2 (g) \rightarrow 12 CO_2 (g) + 6H_2O(g) $ How many litres of $O_2$ at STP are needed to complete the combustion of 39 g of liquid benzene? $(Mol. \, weight \, of \, O_2 = 32, C_6H_6 = 75)$

Updated On: Jul 12, 2022
  • 74 L
  • 11.2 L
  • 22.4 L
  • 84 L
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The Correct Option is D

Solution and Explanation

(d) $2C_6 H_6 + 15O _2 (g) \rightarrow 12CO_2 (g) + 6H_2O(g)$ $_{=156}^{2 \times 78} \, \, \, \, \, _{=330}^{15 \times 32} $ $\therefore$ 156 g of benzene required oxygen $= 15 \times 22.4 L $ $\therefore$ 1 g of benzene required oxygen $= \frac {15 \times 22.4} {156}L$ $\therefore$ 39 g of benzene required oxygen $ = \frac{15 \times 22.4 \times 39} {156}$ = 84.0 L
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Top Questions on Organic Chemistry- Some Basic Principles and Techniques

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Concepts Used:

Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism

SN1 Reaction Mechanism:

SN1 reaction mechanism takes place by following three steps –

  • Formation of carbocation 
  • Attack of nucleophile 
  • Deprotonation 

SN2 Reaction Mechanism:

The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.

Electrophilic Aromatic Substitution Reaction Mechanism:

The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:

  1. A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
  2. Due to the breaking of the C-H sigma bond, a proton is removed.
  3. The C=C bond is reformed and it restores the aromaticity of the compound.

Electrophilic Substitution Reaction Mechanism:

The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.

  • Electrophile Generation
  • Carbocation Formation
  • Proton Removal