Question:

Let \(T_1\) and \(T_2\) be the energy of an electron in the first and second excited states of the hydrogen atom, respectively. According to Bohr’s model of an atom; the ratio T1:T2 is:

Updated On: May 2, 2025
  • \(1:4\)
  • \(4:1\)
  • \(4:9\)
  • \(9:4\)
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The Correct Option is D

Solution and Explanation

To determine the ratio of the energy levels of an electron in different states of a hydrogen atom according to Bohr’s model, we start by understanding how the energy of an electron in a given state is defined. According to Bohr's model, the energy of an electron in the \(n^{th}\) orbit is given by the formula:

\(E_n = -\dfrac{13.6}{n^2}\, \text{eV}\)
where \(E_n\) is the energy in electron volts (eV) and \(n\) is the principal quantum number corresponding to the orbit.

We need to find the energies \(T_1\) for the first excited state and \(T_2\) for the second excited state of the hydrogen atom.
For the first excited state, \(n = 2\):

\(T_1 = -\dfrac{13.6}{2^2} = -\dfrac{13.6}{4}\, \text{eV}\)
For the second excited state, \(n = 3\):

\(T_2 = -\dfrac{13.6}{3^2} = -\dfrac{13.6}{9}\, \text{eV}\)

The absolute value of these energies is used to find the ratio since energy values are negative due to the nature of bound states.

The ratio \(\dfrac{T_1}{T_2}\) is:
 

\(\dfrac{\left|\dfrac{13.6}{4}\right|}{\left|\dfrac{13.6}{9}\right|} =  \dfrac{9}{4}\)

Thus, the ratio of the energies \(T_1:T_2\) is: \(9:4\)

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Concepts Used:

Bohr's Model of Hydrogen Atom

Niels Bohr introduced the atomic Hydrogen model in 1913. He described it as a positively charged nucleus, comprised of protons and neutrons, surrounded by a negatively charged electron cloud. In the model, electrons orbit the nucleus in atomic shells. The atom is held together by electrostatic forces between the positive nucleus and negative surroundings.

Read More: Bohr's Model of Hydrogen Atom

Bohr's Theory of Hydrogen Atom and Hydrogen-like Atoms

A hydrogen-like atom consists of a tiny positively-charged nucleus and an electron revolving around the nucleus in a stable circular orbit. 

Bohr's Radius: 

If 'e,' 'm,' and 'v' be the charge, mass, and velocity of the electron respectively, 'r' be the radius of the orbit, and Z be the atomic number, the equation for the radii of the permitted orbits is given by r = n2 xr1, where 'n' is the principal quantum number, and r1 is the least allowed radius for a hydrogen atom, known as Bohr's radius having a value of 0.53 Å. 

Limitations of the Bohr Model

The Bohr Model was an important step in the development of atomic theory. However, it has several limitations.

  1. Bohr’s model of the atom failed to explain the Zeeman Effect (effect of magnetic field on the spectra of atoms).
  2. It failed to explain the Stark effect (effect of electric field on the spectra of atoms).
  3. The spectra obtained from larger atoms weren’t explained.
  4. It violates the Heisenberg Uncertainty Principle.