From the given, \( P\left( \left( B(2) + 2B(3) \right)>1 \right) = 1 - \Phi\left( \frac{1}{\sqrt{\alpha}} \right) \). To solve for \( \alpha \), we first compute the distribution of \( B(2) + 2B(3) \). Since \( B(t) \) is a standard Brownian motion, the random variable \( B(2) + 2B(3) \) is normally distributed.
The mean of \( B(2) + 2B(3) \) is 0 (because Brownian motion has a mean of 0 at all times), and the variance is given by:
\[
\text{Var}(B(2) + 2B(3)) = \text{Var}(B(2)) + 4\text{Var}(B(3)) + 4\text{Cov}(B(2), B(3)).
\]
Since \( B(2) \) and \( B(3) \) are correlated with covariance \( \text{Cov}(B(2), B(3)) = 2 \), we have:
\[
\text{Var}(B(2) + 2B(3)) = 2 + 4 \times 3 + 4 \times 2 = 2 + 12 + 8 = 22.
\]
Thus, \( B(2) + 2B(3) \sim N(0, 22) \). The probability is given by:
\[
P\left( B(2) + 2B(3)>1 \right) = 1 - \Phi\left( \frac{1}{\sqrt{22}} \right).
\]
From the equation, we match this to \( 1 - \Phi\left( \frac{1}{\sqrt{\alpha}} \right) \). Hence, we find \( \alpha = 22 \).
Thus, the value of \( \alpha \) is \( \boxed{22} \).