Knowing that the Chemistry of lanthanoids $(Ln)$ is dominated by its $+3$ oxidation state, which of the following statements in incorrect ?
- Because of the large size of the $Ln (III)$ ions the bonding in its compounds is predominantly ionic in character
- The ionic sizes of $Ln (III)$ decrease in general with increasing atomic number
- $Ln (III)$ compounds are generally colourless
- $Ln (III)$ hydroxides are mainly basic in character
The Correct Option is C
Solution and Explanation
Top Questions on d -and f -Block Elements
- Match List-I with List-II.Choose the correct answer from the options given below:
List-I
Alkali MetalList-II
Emission Wavelength
in nm(A) Li (I) 589.2 (B) Na (II) 455.5 (C) Rb (III) 670.8 (D) Cs (IV) 780.0 - JEE Main - 2024
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(Given atomic number: \( \text{Sc: 21, Ti: 22, V: 23, Cr: 24, Mn: 25, Fe: 26, Co: 27, Ni: 28, Cu: 29, Zn: 30} \))- JEE Main - 2024
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Concepts Used:
D and F Block Elements
The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements.
They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.
Read More: The d and f block elements