cumene hydroperoxide, phenol, acetone
cumene hydroperoxide, phenol, acetaldehyde
Isopropylbenzene (cumene) is oxidized in the presence of air to form cumene hydroperoxide (X).
On acidic hydrolysis, cumene hydroperoxide breaks down to give:
This reaction is important in industry for the commercial production of phenol and acetone.
X = Cumene hydroperoxide
Y = Phenol
Z = Acetone
Correct Answer: (B) cumene hydroperoxide, phenol, acetone
List-I Compound | List-II Product in Basic Medium (in NaOH + Heat) | ||
A | Ethanal | (I) | Benzoic acid + Phenyl methanol |
B | Methanal | (II) | 3-Hydroxybutanal + But-2-enal |
C | Benzenecarbaldehyde | (III) | 4-Hydroxy-4-methylpentan-2-one + 4-Methylpent-3-en-2-one |
D | Acetone | (IV) | Formic acid + Methanol |
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: