Question:

Indicate the σ and π bonds in the following molecules. \(C_6H_6, C_6H_{12}, CH_2Cl_2, CH_2=C=CH_2, CH3NO2, HCONHCH_3.\)

Updated On: Nov 16, 2023
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Solution and Explanation

(i) C6H6
There are six C-C sigma (σ C-C) bonds, six C–H sigma (σ C-H)  bonds, and three C=C pi (𝜋𝐶−𝐶) resonating bonds in the given compound.  


(ii) ) C6Hl2
 C6Hl2
There are six C-C sigma (σ C-C) bonds and twelve C-H sigma (σ C-H)  bonds in the given compound.


(iii) CH2Cl2
CH2Cl2
There are two C-H sigma (σ C-H) bonds and two C-Cl sigma (σ C-Cl) bonds in the given compound. 


(iv) CH2 = C = CH
CH2 = C = CH
There are two C-C sigma (σ C-C) bonds, four C-H sigma (σ C-H ) bonds, and two C=C pi (σ C-C) bonds in the given compound. 


(v) CH3NO2
CH3NO2
There are three C-H sigma (σ C-H) bonds, one C-N sigma (σ C-N) bond, one N-O sigma (σ N-O) bond, and one N=O PI(π N=O) bond in the given compound.


 (vi) HCONHCH3
 HCONHCH3
There are two C-N sigma (σ C-N) bonds, four C-H sigma (σ C-H) bonds, one N-H sigma bond, and one C=O pi (π C-C) bond in the given compound.

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Top Questions on Organic Chemistry- Some Basic Principles and Techniques

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Concepts Used:

Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism

SN1 Reaction Mechanism:

SN1 reaction mechanism takes place by following three steps –

  • Formation of carbocation 
  • Attack of nucleophile 
  • Deprotonation 

SN2 Reaction Mechanism:

The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.

Electrophilic Aromatic Substitution Reaction Mechanism:

The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:

  1. A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
  2. Due to the breaking of the C-H sigma bond, a proton is removed.
  3. The C=C bond is reformed and it restores the aromaticity of the compound.

Electrophilic Substitution Reaction Mechanism:

The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.

  • Electrophile Generation
  • Carbocation Formation
  • Proton Removal