Question:

In the series $Sc$ to $Zn$, the enthalpy of atomisation of zinc is the lowest. Zinc has greater number of unpaired electrons.

Updated On: Jul 6, 2022
  • If both assertion and reason are true and reason is the correct explanation of assertion
  • If both assertion and reason are true but reason is not the correct explanation of assertion
  • If assertion is true but reason is false
  • If both assertion and reason are false
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The Correct Option is C

Solution and Explanation

Zinc does not have unpaired electrons in ground state as well as in its common oxidation state. Enthalpy of atomisation depends upon the number of unpaired electrons. Greater the number of unpaired electrons, stronger is the interatomic metallic bonding and higher is the enthalpy of atomisation.
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Notes on d -and f -Block Elements

Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

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