List-I | List-II | ||
(A) | [Co(NH3)5(NO2)]Cl2 | (I) | Solvate isomerism |
(B) | [Co(NH3)5(SO4)]Br | (II) | Linkage isomerism |
(C) | [Co(NH3)6] [Cr(CN)6] | (III) | Ionization isomerism |
(D) | [Co(H2O)6]Cl3 | (IV) | Coordination isomerism |
List-I | List-II | ||
(A) | 1 mol of H2O to O2 | (I) | 3F |
(B) | 1 mol of MnO-4 to Mn2+ | (II) | 2F |
(C) | 1.5 mol of Ca from molten CaCl2 | (III) | 1F |
(D) | 1 mol of FeO to Fe2O3 | (IV) | 5F |
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: