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In pyrrole, the electron density is maximum on

Pyrrole

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Aromatic compounds possess a conjugated π-electron system that contributes to their stability and unique properties.

Updated On: Apr 29, 2024
  • 2 and 3
  • 5 and 3
  • 2 and 4
  • 2 and 5
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The Correct Option is D

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The correct answer is Option D) 2 and 5

Pyrrole has the highest electron density at \(C_2\) and \(C_5\) due to the highest stability of protonated intermediate. The resonance structure of pyrrole depicts that the 3rd and 5th structures are stable ones.

Pyrrole resonance structures

Discover More From Chapter: Hydrocarbons

 

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The correct answer is Option D) 2 and 5

Real Life Applications

  • Life cannot exist without the class of substances known as porphyrins, which have a pyrrole ring in their core. Both the protein haemoglobin, which carries oxygen in the blood, and the pigment chlorophyll, which enables photosynthesis in plants, include them. 
  • Some medications also include pyrrole, including the antimalarial medicine chloroquine. Some polymers and colours are produced using pyrrole.

Question can also be asked as

  1. Where is the maximum electron density in pyrrole? 
  2. Why is the electron density maximum on those carbon atoms? 
  3. What are the implications of the maximum electron density on the reactivity of pyrrole? 
  4. How does the electron density in pyrrole change when it is protonated? 
  5. What are the different resonance structures of pyrrole, and how do they affect the electron density?
  6. What is the difference between electron density and charge? 
  7. How is electron density calculated? 
  8. What are the different factors that affect electron density? 
  9. What are the different types of resonance structures? 
  10. How do resonance structures affect the stability of a molecule?
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The correct answer is Option D) 2 and 5

Pyrrole is an aromatic organic compound with a five-membered ring structure. It is known for its aromatic properties.

Electron Density in Aromatic Compounds

  • Aromatic compounds possess a conjugated π-electron system that contributes to their stability and unique properties.
  • These π-electrons are delocalized throughout the ring structure, resulting in regions of high and low electron density.

Electron Density Distribution in Pyrrole

  • In pyrrole, the maximum electron density is observed on the 2nd and 5th positions of the ring.
  • These positions correspond to the carbon atoms adjacent to the nitrogen atom in the pyrrole structure.

Resonance Structure and Electron Delocalization

  • The distribution of electron density in pyrrole is attributed to the resonance structure within the molecule.
  • The lone pair of electrons on the nitrogen atom participates in π-electron delocalization, leading to increased electron density on the adjacent carbon atoms.

Importance of Electron Density Distribution

  • The electron density distribution in pyrrole influences its reactivity and interactions with other molecules.
  • The concentration of electron density on the 2nd and 5th positions contributes to the compound's ability to undergo various chemical reactions.

In pyrrole, an aromatic five-membered ring structure, the electron density is maximum on the 2nd and 5th positions. This electron density distribution is a result of π-electron delocalization and resonance within the molecule. 

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Related Concepts
Bomb CalorimeterConformational IsomersOrganic Solvent
Aliphatic HydrocarbonsCoupling ReactionRate of Reaction
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Hydrocarbons

Hydrocarbons can be described as organic compounds that consists only hydrogen and carbon atoms. These compounds are of different types and thereby have distinct natures. Hydrocarbons are colorless gases and are known for discharging faint odours. These have been categorized under four major classes named as alkynes, alkanes, alkenes, and aromatic hydrocarbons. 

Types of Hydrocarbons

  1. Saturated hydrocarbons - Saturated hydrocarbons are those compounds where there is a single bond exists between carbon atoms and are saturated with atoms of hydrogen.
  2. Unsaturated hydrocarbons - Hydrocarbons comprises of at least one double or triple bond between carbon atoms are known as unsaturated hydrocarbons.
  3. Aliphatic hydrocarbons - The term denotes the hydrocarbons formed as an outcome of the chemical degradation of fats. Aliphatic hydrocarbons are basically chemical compounds.
  4. Aromatic hydrocarbons - They are distinguished because of the presence of benzene rings in them. They give away distinct types of aroma. These hydrocarbons comprises of only hydrogen and carbon atoms.