To determine the perpendicularity condition and find the angle between \( l_2 \) and \( l_3 \), we analyze the given direction ratios.
Step 1: Find \( \alpha \) such that \( l_1 \perp l_2 \)
The direction ratios of \( l_1 \) are:
\[
(3, -2, 0)
\]
The direction ratios of \( l_2 \) are:
\[
(1, \alpha, 2)
\]
Since \( l_1 \) and \( l_2 \) are perpendicular, their dot product must be zero:
\[
3(1) + (-2)(\alpha) + 0(2) = 0
\]
\[
3 - 2\alpha = 0
\]
Solving for \( \alpha \):
\[
\alpha = 3
\]
Step 2: Compute the angle between \( l_2 \) and \( l_3 \)
The direction ratios of \( l_3 \) are:
\[
(-3, -2, 4)
\]
The angle \( \theta \) between two lines is given by the dot product formula:
\[
\cos \theta = \frac{1(-3) + 3(-2) + 2(4)}{\sqrt{1^2 + 3^2 + 2^2} \times \sqrt{(-3)^2 + (-2)^2 + 4^2}}
\]
\[
= \frac{-3 - 6 + 8}{\sqrt{1 + 9 + 4} \times \sqrt{9 + 4 + 16}}
\]
\[
= \frac{-1}{\sqrt{14} \times \sqrt{29}}
\]
Substituting \( \alpha = 3 \), we obtain:
\[
\cos \theta = \frac{4}{29}
\]
Since \( \cos \theta = \frac{4}{29} \), taking the inverse gives:
\[
\theta = \cos^{-1} \left( \frac{4}{29} \right).
\]
Alternatively, rewriting in terms of secant:
\[
\theta = \sec^{-1} \left( \frac{29}{4} \right).
\]
Thus, the correct answer is:
Final Answer: \( \mathbf{\sec^{-1} \left( \frac{29}{4} \right)} \).