Question:

If �a� stands for the edge length of the cubic systems : simple cubic, body centred cubic and face centred cubic, then the ratio of radii of the spheres in these systems will be respectively,

Updated On: Apr 26, 2024
  • $\frac{1}{2} a: \frac{\sqrt{3}}{4} a:\frac{1}{2\sqrt{2}} a$
  • $\frac{1}{2} a: \sqrt{3}a: \frac{1}{\sqrt{2}}a$
  • $\frac{1}{2} a: \frac{\sqrt{3}}{2} a:\frac{\sqrt{3}}{2} a$
  • $1a : \sqrt{3}a: \sqrt{2}a$
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The Correct Option is A

Solution and Explanation

Following generalization can be easily derived for various types of lattice arrangements in cubic cells between the edge length (a) of the cell and r the radius of the sphere.
For simple cubic:$a=2r \,or \, r=\frac{a}{2} $
For body centred cubic :$a=2 \sqrt{2}r \,or\, r=\frac{1}{2\sqrt{2}} a$
Thus the ratio of radii of spheres for these will be
simple: bcc: fcc
$=\frac{a}{2} :\frac{\sqrt{3}}{4} a: \frac{1}{2\sqrt{2}} a i.e.$
option (a) is correct answer.
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Concepts Used:

Unit Cells

The smallest portion of a crystal lattice which repeats in different directions to form the entire lattice is known as Unit cell.

The characteristics of a unit cell are:

  • The dimensions are measured along the three edges, a, b and c. These edges can form different angles, they may be mutually perpendicular or may not.
  • The angles held by the edges are α (between b and c) β (between a and c) and γ (between a and b).

Therefore, a unit cell is characterised by six parameters such as a, b, c and α, β, γ.

Types of Unit Cell:

Numerous unit cells together make a crystal lattice. Constituent particles like atoms, molecules are also present. Each lattice point is occupied by one such particle.

  1. Primitive Unit Cells: In a primitive unit cell constituent particles are present only on the corner positions of a unit cell.
  2. Centred Unit Cells: A centred unit cell contains one or more constituent particles which are present at positions besides the corners.
    1. Body-Centered Unit Cell: Such a unit cell contains one constituent particle (atom, molecule or ion) at its body-centre as well as its every corners.
    2. Face Centered Unit Cell: Such a unit cell contains one constituent particle present at the centre of each face, as well as its corners.
    3. End-Centred Unit Cells: In such a unit cell, one constituent particle is present at the centre of any two opposite faces, as well as its corners.