In uniform circular motion, the velocity of the particle is always tangential to the path. The change in velocity is given by the vector difference between the velocities at points \( P \) and \( Q \).
The velocity vectors at these points subtend an angle \( \theta \) at the center. The magnitude of the change in velocity is given by:
\[
\Delta v = 2v \sin \frac{\theta}{2}
\]
Thus, the correct answer is:
\[
2v \sin \frac{\theta}{2}
\]