Step 1: Relate surface area and side length.
The surface area \( A \) of a cube is given by the formula:
\[
A = 6s^2
\]
where \( s \) is the side length.
Step 2: Solve for the side length.
Substitute the given surface area:
\[
96 = 6s^2
\]
Solving for \( s^2 \):
\[
s^2 = \frac{96}{6} = 16
\]
Thus, \( s = 4 \).
Step 3: Calculate the volume.
The volume \( V \) of a cube is given by:
\[
V = s^3
\]
Substitute \( s = 4 \):
\[
V = 4^3 = 64
\]
Final Answer:
\[
\boxed{64}
\]