Step 1: Use the dilution formula:
\[
C_1 V_1 = C_2 V_2
\]
where,
\( C_1 = 1 \, M \) (initial concentration),
\( V_1 = 100 \, \text{mL} \) (initial volume),
\( C_2 = 0.25 \, M \) (final concentration),
\( V_2 = ? \) (final volume).
Step 2: Calculate \( V_2 \):
\[
V_2 = \frac{C_1 V_1}{C_2} = \frac{1 \times 100}{0.25} = 400 \, \text{mL}
\]
Step 3: Volume of water to be added = Final volume - Initial volume
\[
= 400 - 100 = 300 \, \text{mL}
\]
Step 4: Therefore, 300 mL of water should be added.