Step 1: The system is an Atwood machine with masses
\[
m_1 = 3\,\text{kg}, \quad m_2 = 2\,\text{kg}.
\]
Acceleration of the system:
\[
a = \frac{m_1 - m_2}{m_1 + m_2}g = \frac{1}{5}g = 1.96\,\text{m s}^{-2}.
\]
Step 2: Velocity of the 2 kg mass after 5 s:
\[
v = at = 1.96 \times 5 = 9.8\,\text{m s}^{-1}.
\]
Step 3: After the string breaks, the 2 kg mass moves upward with initial velocity \(9.8\,\text{m s}^{-1}\) against gravity.
Maximum additional height reached:
\[
h = \frac{v^2}{2g} = \frac{(9.8)^2}{2 \times 9.8} = 4.9\,\text{m}.
\]
Step 4: Hence, from the moment the string breaks, the 2 kg mass rises by
\[
\boxed{4.90\,\text{m}}.
\]