Step 1: Understanding the Given Information.
We are given the rate constant \( k = 10^{-3} \) and the time for the reaction to reach 100% completion. We can use the formula for the reaction time \( t_{\text{100%}} \) for a first-order reaction:
\[
t_{\text{100%}} = \frac{2.303}{k}
\]
Where \( k \) is the rate constant and the time is in minutes.
Step 2: Calculation.
\[
t_{\text{100%}} = \frac{2.303}{10^{-3}} = 2303 \, \text{min}
\]
Thus, the time it will take to reach 100% completion is approximately 20 minutes.
Step 3: Conclusion.
The correct answer is (D) 20 min.