Step 1: Determine the Slopes of the Lines
The general form of a homogeneous second-degree equation:
\[
Ax^2 + 2Hxy + By^2 = 0
\]
represents two straight lines. The slopes of these lines are given by:
\[
m_1, m_2 = \frac{- (H \pm \sqrt{H^2 - AB})}{B}.
\]
By comparing this with the equation \( x^2 + kxy - 3y^2 = 0 \), we identify the coefficients:
\[
A = 1, \quad H = \frac{k}{2}, \quad B = -3.
\]
Step 2: Apply the Given Condition
The sum of the slopes is:
\[
m_1 + m_2 = -\frac{2H}{B} = -\frac{k}{-3} = \frac{k}{3}.
\]
The product of the slopes is:
\[
m_1 m_2 = \frac{A}{B} = \frac{1}{-3} = -\frac{1}{3}.
\]
Using the condition \( m_1 + m_2 = 2(m_1 m_2) \), we substitute the known values:
\[
\frac{k}{3} = 2 \times \left(-\frac{1}{3}\right).
\]
\[
\frac{k}{3} = -\frac{2}{3}.
\]
Step 3: Solve for \( k \)
\[
k = -2.
\]