Question:
Elements of group-$15$ form compounds in $+5$ oxidation state. However, bismuth forms only one well characterised compound in $+5$ oxidation state. The compound is
Elements of group-$15$ form compounds in $+5$ oxidation state. However, bismuth forms only one well characterised compound in $+5$ oxidation state. The compound is
Updated On: Jul 6, 2022
- $Bi_2O_5$
- $BiF_5$
- $BiCl_5$
- $Bi_2S_5$
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The Correct Option is B
Solution and Explanation
The stability of $+5$ oxidation state decreases down the group due to inert pair effect. The only well characterised $Bi(V)$ compound is $BiF_5$ as fluorine being most electronegative element is able to unpair $ns$ electrons.
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Top Questions on p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
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Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family