The electrostatic force between two charges is governed by Coulomb's law:
\[
F = \frac{1}{4 \pi \epsilon_0} \cdot \frac{Q_1 Q_2}{r^2}
\]
where \( Q_1 \) and \( Q_2 \) are the magnitudes of the charges and \( r \) is the distance between them.
When a charge is placed on a spherical conductor, the electrostatic force is maximum when the charge is placed at the surface because the charge distributes uniformly over the surface of the sphere. This results in the maximum electrostatic force at the surface.
Thus, the electrostatic force is maximum when the charge \( Q \) is placed at the surface of the sphere.