Point 1: Position in accounts.
\emph{Charge} → recorded in Profit & Loss A/c as expense; reduces profit.
\emph{Appropriation} → recorded in P& L \emph{Appropriation} A/c; allocates profit.
Point 2: Compulsion.
\emph{Charge} is obligatory (must be paid irrespective of profit).
\emph{Appropriation} is discretionary (depends on available profit).
Point 3: Examples.
Charge: Interest on debentures, depreciation.
Appropriation: Dividend, transfer to general reserve, bonus issue.
Final Answer:
\[
\boxed{\text{Charge = before profit; Appropriation = after profit (with examples)}}
\]
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