Question:

Consider the structure of a crosslinked polymer shown in the figure. From the options given, identify the monomers that are used in the synthesis of the polymer.

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Urea–formaldehyde and melamine–formaldehyde are classic amino thermosets; the presence of a triazine ring points to \textbf{melamine}.
Updated On: Aug 29, 2025
  • Melamine and Benzaldehyde
  • Melamine and Acetone
  • Melamine and Formaldehyde
  • Melamine and Ethanol
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The Correct Option is C

Solution and Explanation

Step 1: Recognize the repeat unit in the figure.
The depicted network shows a s-triazine ring (six-membered ring with three nitrogens) carrying –NH groups—this is the core of melamine. The network has methylene/ether bridges indicative of a thermoset.
Step 2: Recall the melamine–formaldehyde (MF) resin formation.
Melamine reacts with formaldehyde to form {methylol melamine} (–NH–CH\textsubscript{2}OH) intermediates. On curing/condensation, these create crosslinks via –NH–CH\textsubscript{2}–NH– and –NH–CH\textsubscript{2}–O–CH\textsubscript{2}–NH– bridges, giving a rigid thermoset network that matches the figure.
Step 3: Eliminate distractors.
Benzaldehyde and acetone are not used to make the MF thermoset; ethanol is not an aldehyde for the condensation needed.
Step 4: Conclude.
Therefore, the polymer is a melamine–formaldehyde resin. Final Answer: \[ \boxed{\text{Melamine and Formaldehyde}} \]
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