Question:

Calculate molar conductivity for 0.5 M BaCl\(_2\) if its conductivity at 298K is 0.01 \( \Omega^{-1} \text{cm}^{-1} \).

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Solution and Explanation

Molar conductivity \( \Lambda_m = \frac{\kappa \cdot 1000}{C} \), where \( \kappa = 0.01 \, \Omega^{-1} \text{cm}^{-1} \), \( C = 0.5 \, \text{mol dm}^{-3} = 0.5 \, \text{mol L}^{-1} = 500 \, \text{mol m}^{-3} \). Convert units: \[ \Lambda_m = \frac{0.01 \cdot 1000}{0.5} = \frac{10}{0.5} = 20 \, \Omega^{-1} \text{cm}^2 \text{mol}^{-1}. \]
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