Confinement in nanomaterials refers to the restriction of particle movement in one or more dimensions.
• Bulk Material: There is no confinement and particles have freedom of movement in all the dimensions.
• Quantum Well: The particles are confined in one dimension only.
• Carbon Nanotube: Particles are confined to two dimensions (moving along the tube).
• Quantum Dot: Particles are confined in all three dimensions leading to quantum confinement.
Therefore, the order of increasing confinement is Bulk material <Quantum well <Carbon nanotube <Quantum dot.