The initial state of the air:
\[
P_1 = 1\ \text{MPa}, \qquad T_1 = 600\ \text{K}, \qquad V = 10\ \text{m}^3
\]
For an ideal gas, we use the relation:
\[
PV = mRT
\]
We know the final temperature is $T_2 = 400$ K, and the process is isochoric (constant volume). Therefore, the pressure ratio can be derived as:
\[
\frac{P_2}{P_1} = \frac{T_2}{T_1}
\]
\[
P_2 = P_1 \times \frac{T_2}{T_1} = 1 \times \frac{400}{600} = 0.6667\ \text{MPa}
\]
Hence, the final pressure of the air in the tank is:
\[
\boxed{0.67\ \text{MPa}}
\]