Ti+, V4+, Cr6+, Mn7+
Ti4+, V3+, Cr2+, Mn3+
Ti2+, V3+, Cr4+, Mn5+
Ti3+, V2+, Cr3+, Mn4+
The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
What is crystal field splitting energy?
The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
On the basis of CFT, explain why [Ti(H$_2$O)$_6$]Cl$_3$ complex is coloured? What happens on heating the complex [Ti(H$_2$O)$_6$]Cl$_3$? Give reason.
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.