Acid rain is primarily caused by the emission of two specific gases: nitrogen oxides (NOx) and sulfur dioxide (SO₂). When these gases are released into the atmosphere, they react with water vapor, oxygen, and other chemicals to form acidic compounds. This process can be elucidated by the following reactions:
- Sulfur Dioxide (SO₂): SO₂, once in the atmosphere, can be oxidized to form sulfur trioxide (SO₃), which subsequently reacts with water to produce sulfuric acid (H₂SO₄). The chemical reactions can be represented as:
SO₂ + O₂ → SO₃
SO₃ + H₂O → H₂SO₄ - Nitrogen Oxides (NOx): Nitrogen oxides, primarily nitrogen monoxide (NO) and nitrogen dioxide (NO₂), participate in forming nitric acid (HNO₃). This process involves the oxidation of NO to NO₂, followed by reacting with water:
2NO + O₂ → 2NO₂
3NO₂ + H₂O → 2HNO₃ + NO
As a result, these acids precipitate onto the earth's surface, causing environmental harm to ecosystems, buildings, and infrastructure. Therefore, the correct answer is "Nitrogen oxides and sulfur dioxide".