Step 1: Bound charge densities.
The surface bound charge density is given by
\[
\sigma_b = \vec{P} \cdot \hat{n}
\]
At \(r = a\), the normal \(\hat{n}\) is inward, so \(\sigma_b(a) = -\dfrac{k}{a^2}\).
At \(r = b\), the normal \(\hat{n}\) is outward, so \(\sigma_b(b) = +\dfrac{k}{b^2}\).
Step 2: Volume bound charge density.
The volume bound charge density is
\[
\rho_b = -\nabla \cdot \vec{P}
\]
Since \(\vec{P} = \dfrac{k}{r^2}\hat{r}\),
\[
\nabla \cdot \vec{P} = \dfrac{1}{r^2} \dfrac{d}{dr}(r^2 P_r) = \dfrac{1}{r^2} \dfrac{d}{dr}(r^2 \times \dfrac{k}{r^2}) = 0
\]
Thus, \(\rho_b = 0\).
Step 3: Conclusion.
Hence, surface charge densities are \(-k/a^2\) and \(+k/b^2\), and there is no volume bound charge inside.

At a particular temperature T, Planck's energy density of black body radiation in terms of frequency is \(\rho_T(\nu) = 8 \times 10^{-18} \text{ J/m}^3 \text{ Hz}^{-1}\) at \(\nu = 3 \times 10^{14}\) Hz. Then Planck's energy density \(\rho_T(\lambda)\) at the corresponding wavelength (\(\lambda\)) has the value \rule{1cm}{0.15mm} \(\times 10^2 \text{ J/m}^4\). (in integer)
[Speed of light \(c = 3 \times 10^8\) m/s]
(Note: The unit for \(\rho_T(\nu)\) in the original problem was given as J/m³, which is dimensionally incorrect for a spectral density. The correct unit J/(m³·Hz) or J·s/m³ is used here for the solution.)