Given below are the four isomeric compounds \(P, Q, R, S\): 
\(P\): Aromatic compound containing an \(-\mathrm{OH}\) group
\(Q\): Aromatic compound containing an \(-\mathrm{CHO}\) group (aldehyde)
\(R\): Aromatic compound containing a ketone group
\(S\): Aromatic compound containing a ketone group Identify the correct statements from below:
[A.] \(Q, R\) and \(S\) will give precipitate with \(2,4\)-DNP.
[B.] \(P\) and \(Q\) will give positive Baeyer’s test.
[C.] \(Q\) and \(R\) will give sooty flame.
[D.] \(R\) and \(S\) will give yellow precipitate with \(I_2/\mathrm{NaOH}\).
[E.] \(Q\) alone will deposit silver with Tollens’ reagent. Choose the correct option.
Match the LIST-I with LIST-II 
Choose the correct answer from the options given below:

The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below. 
The slope of the line is \(0.36 \times 10^2\) s, and the y-intercept is \(1.20\) mol\(^{-1}\) L s. The value of the Michaelis constant (\(K_M\)) is ________ \( \times 10^{-3} \) mol L\(^{-1}\) (in integer). [Note: \(v\) is the initial rate, and \([S]_0\) is the substrate concentration]
The expressions for the vapour pressure of solid (\( p_1 \)) and vapour pressure of liquid (\( p_2 \)) phases of a pure substance, respectively, are \[ \ln p_1 = \frac{-2000}{T} + 5 \quad {and} \quad \ln p_2 = \frac{-4000}{T} + 10 \] The triple point temperature of this substance is __________ K (in integer).
The ratio of the fundamental vibrational frequencies \( \left( \nu_{^{13}C^{16}O} / \nu_{^{12}C^{16}O} \right) \) of two diatomic molecules \( ^{13}C^{16}O \) and \( ^{12}C^{16}O \), considering their force constants to be the same, is ___________ (rounded off to two decimal places).
The specific rotation of enantiomerically pure (S)-2-butanol is \( +14^\circ \). The specific rotation of the enantiomeric mixture of 2-butanol obtained from an asymmetric reduction of 2-butanone is found to be \( +7^\circ \). The percentage of (R)-2-butanol present in the reaction mixture is ____________ (in integer).}
Partial hydrolysis of a pentapeptide yields all possible tripeptides and dipeptides. The dipeptides that are obtained upon hydrolysis are given below: Val-Ala Gln-His Phe-Val Ala-Gln
The total number of tripeptides obtained that contain ‘Ala’ as one of the amino acids is __________