Step 1: Possible numbers.
Faces are numbered 1 to 6.
Step 2: Possible products.
All products $i \times j$ where $i, j \in \{1,2,3,4,5,6\}$.
Step 3: Compute unique values.
Products:
- With 1: {1,2,3,4,5,6}
- With 2: {2,4,6,8,10,12}
- With 3: {3,6,9,12,15,18}
- With 4: {4,8,12,16,20,24}
- With 5: {5,10,15,20,25,30}
- With 6: {6,12,18,24,30,36}
Unique products = {1,2,3,4,5,6,8,9,10,12,15,16,18,20,24,25,30,36}.
Step 4: Count.
Total unique values = 18.
Final Answer:
\[
\boxed{18}
\]