Let the velocity of the boat be \( v_b = 13 \, {m/s} \) and the velocity of the river be \( v_r = 12 \, {m/s} \). The time saved by following the quickest path is given as \( \Delta t = 8 \, {s} \).
Step 1: Without the river current, the time to cross the river would be: \[ t_1 = \frac{d}{v_b} \] Step 2: With the river current, the effective velocity of the boat across the river is \( \sqrt{v_b^2 - v_r^2} \). The time to cross the river is: \[ t_2 = \frac{d}{\sqrt{v_b^2 - v_r^2}} \] Step 3: The time saved is the difference between these times: \[ \Delta t = t_1 - t_2 = 8 \] Substituting the given values \( v_b = 13 \, {m/s} \) and \( v_r = 12 \, {m/s} \): \[ \frac{d}{13} - \frac{d}{\sqrt{13^2 - 12^2}} = 8 \] \[ \frac{d}{13} - \frac{d}{\sqrt{25}} = 8 \] \[ \frac{d}{13} - \frac{d}{5} = 8 \] Multiplying both sides by 65: \[ 5d - 13d = 8 \times 65 \] \[ -8d = 520 \] \[ d = 65 \, {m} \] Thus, the width of the river is 65 meters, i.e., option (A).


Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))