When the block is subjected to an electric field, the force on the block due to the electric field is given by:
\[
F = qE
\]
This force acts on the block in the direction of the electric field. Additionally, there is a tension \( T \) in the string that prevents the block from accelerating along the surface. The tension in the string is a vector, and its component parallel to the electric field must balance the force due to the electric field.
When the string becomes parallel to the electric field, the tension \( T \) in the string balances the electric force:
\[
T = 3qE
\]
Thus, the correct answer is option (4), \( 3qE \).