Question:

A black powder when heated with cone. HClHCl gives a greenish yellow gas. The gas acts as an oxidising and a bleaching agent. When it is passed over slaked lime, a white powder is formed which is a ready source of gas. The black powder and white powder respectively are

Updated On: Jul 5, 2022
  • KCIO3KCIO_3 and NaClO3NaClO_3
  • MnO2MnO_2 and Ca(OCl)2Ca(OCl)_2
  • MnO2MnO_2 and KClO3KClO_3
  • MnCl4MnCl_4 and COCl2COCl_2
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The Correct Option is B

Solution and Explanation

MnO2Black powder+\underset{\text{Black powder}}{ {MnO2}}+ 4HCl(conc.)\underset{\text{(conc.)}}{ {4HCl}}>MnCl2+2H2O+ {-> MnCl2 +2H2O +} Cl2Greenish yellow gas\underset{\text{Greenish yellow gas}}{ {Cl2}} Cl2+H2O2HCl+[O] {Cl2 +H2O \to 2HCl +[O]} Coloured matter +[O]> {+[O] ->} Colourless matter 2Ca(OH)2Slaked lime+2Cl2>\underset{\text{Slaked lime}}{ {2Ca(OH)2}}+ {2Cl2 ->} $\underset{\text{Bleaching powder (white)}}{ {Ca(OCl)2}}+ {CaCl2 +2H2O}$
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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: