100 calories of heat is given to a gas in a vessel fitted with a movable piston. The gas does 40 joules of work in expansion. The increase in internal energy is
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The first law of thermodynamics ties heat, work, and internal energy. When heat is in calories, always convert to joules using 1, calorie = 4.184,J. This is especially useful in thermodynamic problems involving energy balance.
From the first law of thermodynamics: \[\Delta U = Q - W\] Given \(Q = 100 \, \text{calories} = 100 \times 4.184 \, \text{J} = 418.4 \, \text{J}\) and \(W = 40 \, \text{J}\): \[\Delta U = 418.4 - 40 \approx 318 \, \text{J}\]