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List of top Chemistry Questions on Haloalkanes and Haloarenes asked in AIIMS
Chlorobenzene is more reactive than benzene towards the electrophilic substitution reaction. Resonance destabilises the carbocation.
AIIMS - 2016
AIIMS
Chemistry
Haloalkanes and Haloarenes
Arrange the given compounds in decreasing order of boiling points.
AIIMS - 2016
AIIMS
Chemistry
Haloalkanes and Haloarenes
Arrange the given set of compounds in order of increasing boiling points. I.
1
1
1
-chloropropane II. Iso-propyl chloride III.
1
1
1
-chlorobutane
AIIMS - 2015
AIIMS
Chemistry
Haloalkanes and Haloarenes
The factor of
Δ
G
\Delta G
Δ
G
values is important in metallurgy. The
Δ
G
\Delta G
Δ
G
values for the following reactions at
80
0
∘
C
800^{\circ} C
80
0
∘
C
are given as
S
2
(
g
)
+
2
O
2
(
g
)
⟶
2
S
O
2
(
g
)
;
Δ
G
=
−
544
k
J
S _{2}(g)+2 O _{2}(g) \longrightarrow 2 SO _{2}(g) ; \Delta G=-544 \,kJ
S
2
(
g
)
+
2
O
2
(
g
)
⟶
2
S
O
2
(
g
)
;
Δ
G
=
−
544
k
J
2
Z
n
(
s
)
+
S
2
(
g
)
⟶
2
Z
n
S
(
s
)
;
Δ
G
=
−
293
k
J
2 Zn (s)+ S _{2}(g) \longrightarrow 2 ZnS (s) ; \Delta G=-293 \,kJ
2
Z
n
(
s
)
+
S
2
(
g
)
⟶
2
Z
n
S
(
s
)
;
Δ
G
=
−
293
k
J
2
Z
n
(
s
)
+
O
2
(
g
)
⟶
2
Z
n
O
(
s
)
;
Δ
G
=
−
480
k
J
2 Zn (s)+ O _{2}(g) \longrightarrow 2 ZnO (s) ; \Delta G=-480\, kJ
2
Z
n
(
s
)
+
O
2
(
g
)
⟶
2
Z
n
O
(
s
)
;
Δ
G
=
−
480
k
J
The
Δ
G
\Delta G
Δ
G
for the reaction,
2
Z
n
S
(
g
)
+
3
O
2
(
g
)
⟶
2
Z
n
O
(
g
)
+
2
S
O
2
(
g
)
2 ZnS (g)+3 O _{2}(g) \longrightarrow 2 ZnO (g)+2 SO _{2}(g)
2
Z
n
S
(
g
)
+
3
O
2
(
g
)
⟶
2
Z
n
O
(
g
)
+
2
S
O
2
(
g
)
will be
AIIMS - 2015
AIIMS
Chemistry
Haloalkanes and Haloarenes
Treatment of chloroethane with a saturated solution of
A
g
C
N
AgCN
A
g
CN
gives ethyl isocyanide as the major product. Cyanide
(
C
N
−
)
\left( CN ^{-}\right)
(
C
N
−
)
is an ambident nucleophile.
AIIMS - 2014
AIIMS
Chemistry
Haloalkanes and Haloarenes
Chloroform is stored in dark coloured bottles. Chronic chloroform exposure may cause damage to liver and kidneys.
AIIMS - 2014
AIIMS
Chemistry
Haloalkanes and Haloarenes
Which of the following compounds are optically active?
AIIMS - 2012
AIIMS
Chemistry
Haloalkanes and Haloarenes
S
N
2
S_N2
S
N
2
reaction readily occurs in
AIIMS - 2011
AIIMS
Chemistry
Haloalkanes and Haloarenes
Which of the following molecules will not show optical activity?
AIIMS - 2008
AIIMS
Chemistry
Haloalkanes and Haloarenes
Which of the following compounds has the highest boiling point?
AIIMS - 2006
AIIMS
Chemistry
Haloalkanes and Haloarenes
3
3
3
-Phenylpropene on reaction with
H
B
r
HBr
H
B
r
gives (as a major product)
AIIMS - 2005
AIIMS
Chemistry
Haloalkanes and Haloarenes
Among the following, the most reactive towards alcoholic
K
O
H
KOH
K
O
H
is :
AIIMS - 2004
AIIMS
Chemistry
Haloalkanes and Haloarenes
Which of the following is involved in Sandmeyer's reaction?
AIIMS - 2002
AIIMS
Chemistry
Haloalkanes and Haloarenes
What happens when chloroform is left open in air in the presence of sunlight?
AIIMS - 1996
AIIMS
Chemistry
Haloalkanes and Haloarenes
When alkyl halides are heated with dry
A
g
2
O
Ag_2O
A
g
2
O
, they give
AIIMS - 1994
AIIMS
Chemistry
Haloalkanes and Haloarenes
When chloroform is exposed to air and sunlight, it gives
AIIMS - 1994
AIIMS
Chemistry
Haloalkanes and Haloarenes